The second law of thermodynamics asserts that processes occur in a certain direction and that the energy has quality as well as quantity.The first law places no restriction on the direction of a process, and satisfying the first law does not guarantee that the process will occur. Thus, we need another general principle (second law) to identify whether a process can occur or not. Fig. above shows Heat transfer process can occur when and only when it satisfies both the first and the second laws of thermodynamics. The second law also asserts that energy has a quality. Preserving the quality of energy is a major concern of engineers. In the above example, the energy stored in a hot container (higher temperature) has higher quality (ability to work) in comparison with the energy contained (at lower temperature) in the surroundings. The second law is also used in determining the theoretical limits for the performance of commonly used engineering systems, such as heat engines and refrig...